Disorienting things make you feel confused. It's disorienting each time you step out of a subway station in a big city — it takes a minute to get your bearings and figure out which direction to walk.

Waking up from the anesthetic after having your wisdom teeth removed is very disorienting, and a disorienting first day at a new school shouldn't be surprising. The adjective disorienting comes from disorient, or "make someone lose their sense of direction," which has a French source, désorienter, "to cause to lose one's bearings," or literally, "to turn from the east."

Definitions of disorienting
  1. adjective
    causing loss of physical or intellectual bearings
    “making so many turns to the right and then the left was completely disorienting
    “a sharp blow to the head can be disorienting
    not having position or goal definitely set or ascertained
    causing confusion or disorientation
    making one feel out of place or alienated
    causing or capable of causing bewilderment or shock or insensibility
    making physically stupid or dull or insensible
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    orientating, orienting
    positioning with respect to a reference system or determining your bearings physically or intellectually
    orientated, oriented
    adjusted or located in relation to surroundings or circumstances; sometimes used in combination
    aligning, positioning
    causing to fall into line or into position
    indicating or determining size and position in space
    familiarising, familiarizing
    serving to make familiar
    orienting or directing homeward or to a destination
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